Don’t worry, it’s not as complicated to program a remote as you think. I did it and I’m a newbie to doing these kinds of things. Unfortunately, to me it sounds like your problem isn’t the key fob. If the electric unlock switch on your drivers door isn’t working, a new key fob won’t fix your issue. The power lock could be dead or you could have a wiring issue. A common problem I’ve observed is the rod that goes in the door to the lock pull will start sticking and needs lubricant at the joints. But I have seen dead electric locks on two Reattas.
Does the electric release button in the glovebox work to unlock/pop your trunk?