I did make an approximate sixty degree face angle exhaust valve using my vertical lathe, aka, drill press😎 While it does contact the wide exhaust seat, and would probably narrow the 45* part, it would take forever as a valve grinder rather than an actual cutter, so I scrapped that idea.
I reassembled the heads this morning after a little spritz of black paint. Of course they look just like when I started from this angle. Retirement party to go too but maybe heads get installed tomorrow